Recycling hydrogen generator

ABSTRACT

The recycling hydrogen generator is an interactive system of chlorine filters and compartments for the reuse of electrolytic residue in hydrogen generation, including various size and type anodes and cathodes controlling the rate of hydrogen production; a pressure sensor and cut-off switch for the electricity to the terminals; and a breakable window for the instant remix of the electrolytic residue; all of which are required to ensure safety in the application of this small scale generator to individual automobile and home use.

CROSS-REFERENCE TO RELATED APPLICATIONS

Application Ser. No. 14/544,986 Filed Mar. 13, 2015

Application Ser. No. 14/544,986 Filed May 27, 2015

FEDERALLY SPONSORED

Not Applicable

NAMES OF PARTIES TO JOINT RESEARCH AGREEMENT

Not Applicable

COMPACT DISC OR TEXT FILE (EFS-WEB)

Not Applicable

STATEMENT OF PRIOR DISCLOSURES

Not Applicable

BACKGROUND OF THE INVENTION

1.) Field of Invention

Hydrogen generator

2.) Description of Related Art

-   -   A) U.S. Pat. No. 899,403A; Date August 1975, Cook, Jr., Edward         H.     -   B) U.S. Pat. No. 9,217,203, Date December 2015, Gotheil-Yelle,         Scott     -   C) Published Ref.: “21 Years of Creative Work” by George         Manojlovich, copyrighted 1977, pages 42-48 (Copy enclosed)

BRIEF SUMMARY

The Recycling Hydrogen Generator is a safety compliant, flexible combination of filters and compartments for removing sodium and chlorine from the electrolysis process of generating hydrogen from water by remixing or recycling the NaOH+HCl residue into NaCl+H₂O for reuse, allowing for the safe generation of hydrogen for individual automobile and home use as a source of electricity.

The flexibility is extended by anodes and cathodes with larger surface area or by the connection of multiple insulated anodes to each other and multiple insulated cathodes connected to each other, which control the rate of hydrogen production, but which requires an attached hydrogen storage tank with a pressure sensor, rheostat and cut-off switch to cut off the electricity causing the electrolysis.

The addition of a breakable window between compartments allows for the instant remix of NaOH accident.

The Recycling Hydrogen Generator combines and thereby improves upon various common knowledge technologies which have been patented or discovered while working with the chlor-alkali process.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

FIG. 1: depicts the recycling hydrogen generator. Internal Side View of chlorine gas filtration system

FIG. 2: depicts the recycling hydrogen generator Internal Side View of expanded surface anode and cathode in expanded compartment comprised of compartments labeled C-1, C-2 and C-3.

FIG. 3: depicts the recycling hydrogen generator Top View of the expanded surface anode and cathode

FIG. 4: depicts the recycling hydrogen generator Internal Side View of further expanded surface area comprising electrically connected, insulated wire mesh cylinders, where anodes are vented at one level and cathodes at a higher level.

FIG. 5: depicts the recycling hydrogen generator Internal End View of alternating wire mesh anodes and cathodes with venting system.

DETAILED DESCRIPTION OF THE INVENTION

In FIG. 1 Internal Side View of chlorine gas filtration system shows the division of the approximately 12″×8″×12″ sturdy, acid-resistant, plastic housing into five compartments labeled C#1-C#5. The Figure (it) shows in C#1 the anode used for electrolysis, a vent or digitally controlled, re-sealable opening in the upper side for the addition of more salt water, and a re-sealable tube adjacent to the anode for the extraction of chlorine gas into compartment C#4. Compartment C#1 is divided from compartment C#2 by a broken line representing the PEM (permeable ion-exchange membrane) or ion-selective membrane which allows hydrogen and oxygen atoms to pass through it (after electrolysis has split the NaCl molecules) but not the chlorine or sodium atoms or H₂O molecules. A vent on the bottom of C#1 extends across the bottom of C#2, to allow the liquid remaining in both compartments, after electrolysis, to fall by gravity into compartment C#3. A breakable window on the left side of C#1 extends to the lower left side of C#3 so that in case of accident, water will mix with the chlorine gas immediately before any can enter the outside atmosphere due to damage to the outside housing or box, forming HCl, such as found in a normal car battery, which is much less dangerous than chlorine gas. FIG. 1 shows that compartment C#2 contains a cathode at the top with an adjacent closeable tube for the removal of hydrogen to a storage tank, and a vent for the addition of clean distilled water It shows that C#3 contains a vent on the lower left side for chlorine gas to be pumped from C#4 into the bottom of the solution in C#3 where the water or weak HCl serves as an additional filter (Filter 2) for the chlorine gases pumped into C#3, some of which will float to the surface, where a second vent above the solution level on the right side pumps any remaining chlorine gases created by disproportionality during electrolysis through a tube to the bottom of C#5 and a re-sealable vent on the bottom side which connects to the discharge or re-cycling tube for the liquid in C#3. FIG. 1 shows that compartment C#4 contains chlorine gas. It connects to the re-sealable chlorine gas tube adjacent to the anode in C#1. A vent on the bottom right internal wall allows the chlorine gas to be siphon pumped into the solution in C#3 to become HCl, and the breakable safety window that extends across the sides of both C#1 and C#3. Finally FIG. 1 shows that compartment C#5 has a vent and a tube from C#3 (above the solution level) to the bottom of C#5 where any remaining oxygen and chlorine gases can be filtered through a NaOH filter (Filter 3) and then a BaO₂ filter (Filter 4) before being released from the generator so that only oxygen is a byproduct entering the atmosphere. In FIGS. 2 and 3, compartments C#4 and C#5 remain the same (although if C#3 also remains the same, the filtration system is improved), but the central combined compartment has the addition of a very large surface zinc or zinc-plated or gold-plated (or half zinc-plated and half gold plated) titanium or steel anode where zinc draws chlorine to it to form zinc-chloride, a solid which can be removed during maintenance cleaning while gold draws oxygen and an equal size and shape rare metal or rare metal plated (preferably palladium which draws hydrogen) cathode. The zinc anode forms another filter (Filter 5) for removing chlorine gases, transforming them into less dangerous zinc-chloride. FIG. 4 and FIG. 5 show an even larger surface anode and cathode system for a faster rate of hydrogen production comprising cylindrical or rectangular, zinc or gold plated wire mesh tubes as anodes and palladium-plated wire mesh tube cathodes, which are electrically connected anode to anode and cathode to cathode, but each individually insulated by a plastic wall sealed to the top of the combined housing compartment but not touching the bottom of said combined housing compartment, where NaOH collects as a heavier molecule than hydrogen, oxygen or chlorine gas. There is a vent attached to the internal side wall of the said combined housing compartment to add fresh water. C#3, C#4 and C#5 remain the same, but a vent above each anode opens into a tube connected to C#4; while a vent above each cathode opens into a separate tube on a higher level for removal of hydrogen to a hydrogen storage tank. The said anodes and cathodes are spaced alternatively with anodes on one side of the said combined compartment and cathodes on the other so as to have access to the collection tube or vent level designated for them.

These variations in compartment size and anode and cathode size in FIGS. 2, 3, 4, and 5 cause varying rates of hydrogen production and they all require an external hydrogen storage tank attached to the other end of the hydrogen collector tube from the cathode equipped with a pressure sensor, rheostat, and electrical cut-off switch to stop hydrogen production when the tank is full. They also require an external vibration system to remix the NaOH+HCl into NaCl+H₂O; as well as to remove the hydrogen from the palladium cathode (Filter 6) and the chlor from the zinc anode (Filter 5) unless these processes are controlled manually. 

1-3. (canceled)
 4. A sturdy, acid-resistant, approximately 12″×8″×12″ plastic housing divided into five or less compartments, labeled C-1 through C-5 and five or more or less filters comprising a flexible and adaptable filtration system for preventing chlorine gases from escaping into the atmosphere during the electrolysis of salt water for the generation of hydrogen by applying electricity to the anode and cathode contained in the said C-1 and C-2 compartments or the combined said C-1 and C-2 compartment.
 5. The housing in claim 4 comprising five compartments, labeled C-1 through C-5, where said C-1 is divided from said C-2 by an ion permeable membrane or PEM which allows only hydrogen and oxygen atoms to pass through it during the electrolysis of salt water, but not the larger sodium, or chlorine atoms or H₂O molecules (Filter 1), where the said C-1 contains the anode and salt water, while the said C-2 contains the cathode and distilled water: a re-sealable vent across the bottom said C-1 and said C-2 allowing the solution to fall by gravity into C-3, where said solution is a filter (Filter 2) for the chlorine gas which is collected at the anode and siphon pumped through compartment C-4 into the bottom of said compartment C-3 or created by disproportionality in general during the electrolysis process: where the said chlorine gas rises through the said solution in C-3, the said chlorine gas being lighter than the NaOH, HCl and H₂O residue molecules comprising the said C-3 solution.
 6. The residual solution in claim 5 contained in compartment C-3 comprising NaOH, HCl and H₂O is re-mixed by vibration of the said housing of claim 4 into NaCl, HCl and H₂O so that it can be removed for reuse or recycling as fresh electrolyte; while any remaining disproportionally created chlorine gas atoms rising to the surface are siphon pumped into the bottom of compartment C-5, where they are trapped by an NaOH filter (Filter 3) and a barium peroxide filter (Filter 4), allowing only oxygen and hydrogen to enter the atmosphere.
 7. The housing in claim 4 comprised of four compartments where compartments C-1 and C-2 are combined by the absence of the PEM, but said C-1 and said C-2 combined still retain an anode and a cathode, while C-3 where the residue solution from said C-1 and said C-2 comprises Filter 2 for extraneous chlorine gases and after remixing by vibration; while the said solution in said compartment C-3 provides recycled fresh electrolyte for the said combined compartments C-1 and C-2 containing the anode and the cathode: while compartments C-4 and C-5 remain the same.
 8. The approximately 12″×8×12″ housing in claim 4 comprises a sufficiently small scale unit for use in individual automobiles and homes to generate hydrogen for the production of electricity.
 9. The anode in claims 4, 5, and 7 comprising a zinc or zinc-plated titanium or steel rod or extended surface (represented in FIGS. 2 and 3) will collect chlorine gases as a solid zinc-chloride (Filter 6), allowing the rod to be removed and cleaned of extraneous chlorine.
 10. The anode in claims 4, 5, and 7 comprising a gold, gold-plated or half gold and half zinc plated extended surface (represented in FIGS. 2 and 3) will attract oxygen atoms allowing hydrogen atoms to be attracted more freely to the cathode in claims 4,5, and
 7. 11. The anode in claims 4,5,7,9, and 10 having an even further extended surface comprising cylindrical or rectangular wire mesh tubes connected to each other electrically from the anode terminal, attached to vents above the electrolyte solution level for removal of oxygen and chlorine gases through the first ventilation level to compartment C-4; alternating with tubular wire mesh cathodes attached to vents in the upper second ventilation level for the extraction of hydrogen; and all said wire mesh tubes individually insulated from each other by plastic walls sealed to the bottom of the said first ventilation level and extending through the said electrolyte solution to 1″ or less above the bottom of the said combined C-1 and C-2 compartments for free mixture by gravity of NaOH and HCl, which are heavier molecules than oxygen, chlorine gas or hydrogen.
 12. The cathode in claims 4, 5, 7, and 11 comprising a rare metal or rare metal-plated titanium or steel rod, extended surface or electrically connected series of wire mesh tubes; said rare metal comprising gold or palladium where said palladium, as demonstrated by prior art, is immediately blocked by hydrogen atoms causing increasing congestion of hydrogen in the said individual, insulated enclosures, requiring an electrically initiated vibration of said cathode to release said hydrogen atoms into the upper second level ventilation tube of claim
 11. 13. The recycling hydrogen generator requires an external storage tank comprising a sturdy, safe housing, a vent connected to the hydrogen generation exit vent or tube and a pressure sensor connected to a rheostat and electrical cut-off switch attached to the source of electricity for the anode and cathode. 